amines have higher melting point then corresponding hydrocarbon of similar molecular mass due to
1.vanderwaals force of attraction
2.intermolecular Hbonding
3.ionic bonding
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amines have higher melting point then corresponding hydrocarbon of similar molecular mass due to
1.vanderwaals force of attraction
2.intermolecular Hbonding
3.ionic bonding
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Explanation:
Piperidine and N-methylpiperidine hydrates aggregate in liquid aqueous solutions due to hydrogen bonds between hydration water molecules. No such effects occur in the mixtures of the amines with methanol, that supports the idea of active role of water solvent in the aggregation.