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Explanation:
Vibrational analysis of band system:-
In the energy Scale, taking the minimum of the potential energy
curve as zero, the vibrational term value E (υ) is given by
( ) = = +
− +
+ +
− − − −
In vibration analysis of the spectrum of a band system, the energy of
the υ=0 vibrational level is taken as zero. That is in the modified
system the vibrational trem
( ) = =
−
+
− − − ( = )............